华西口腔医学杂志 ›› 2008, Vol. 26 ›› Issue (05): 556-559.

• 专栏论著 • 上一篇    下一篇

牙科着色氧化钇稳定四方多晶氧化锆陶瓷的制备及颜色性能

伊元夫1,王晨2,田杰谟2,刘洪臣3,温宁3   

  1. 1.武警总医院口腔科,北京100039;2.清华大学新型陶瓷与精细工艺国家重点实验室,北京100084;3.解放军总医院口腔科,北京100853
  • 收稿日期:2008-10-25 修回日期:2008-10-25 出版日期:2008-10-20 发布日期:2008-10-20
  • 通讯作者: 伊元夫,Tel:010-88276696
  • 作者简介: 伊元夫(1973-),男,辽宁人,副主任医师,博士
  • 基金资助:

    国家自然科学基金资助项目(30700961)

Preparation and chromaticity properties of colored dental 3Y-TZP ceramics

YI Yuan-fu1, WANG Chen2, TIAN Jie-mo2, LIU Hong-chen3, WEN Ning3   

  1. 1. Dept. of Stomatology, The General Hospital of Chinese People′s Armed Police Forces, Beijing 100039, China; 2. State Key Laboratory of New Ceramics and Fine Processing, Tsinghua University, Beijing 100084, China; 3. Dept. of Stomatology, The General Hospital of Chinese PLA, Beijing 100853, China
  • Received:2008-10-25 Revised:2008-10-25 Online:2008-10-20 Published:2008-10-20
  • Contact: YI Yuan-fu,Tel:010-88276696

摘要:

目的添加不同着色剂组合配制着色的牙科氧化钇稳定四方多晶氧化锆(3Y-TZP)陶瓷,并测定其颜色性能。方法将TZ-3Y-S粉体与一定组分的着色剂球磨混合后,在200 MPa压力下等静压成型,在1 500 ℃烧结2 h,烧制5种具有一定颜色的氧化锆材料,每个颜色组分别制备10 mm×10 mm×0.5 mm和10 mm×10 mm×1 mm着色氧化锆陶瓷片,在黑色背景下用柯尼卡美能达CM-2600d分光光度计进行颜色测定,并与VITA In-Ceram YZ染色液比色板颜色作比较。结果通过对粉体进行着色,配制出具有一定颜色的本体着色氧化锆陶瓷材料,颜色明度逐级降低,饱和度逐渐增大,2种厚度3Y-TZP陶瓷的颜色片色差较小,颜色空间范围是L*:67.76~77.78;a*:-2.19~3.80;b*:12.13~25.01。与VITA In-Ceram YZ染色液比色板相比,颜色空间近似,但明度的最低值仍较高。结论着色氧化锆陶瓷材料适宜用于临床上与饰面瓷颜色匹配,有必要再进一步研究低明度的着色氧化锆色片。

关键词: 牙科陶瓷, 氧化锆, 颜色

Abstract:

Objective To obtain and investigate the chromaticity properties of colored dental 3Y-TZP ceramics with different colorant combinations. Methods Colorant combinations were mixed with TZ-3Y-S powder, then the mixtures were compacted at 200 MPa using cold isostatic pressure, densely sintered at 1 500 ℃ for 2 h forming 5 graded colored dental zirconia ceramics. Specimen were sectioned into 10 mm×10 mm×0.5 mm and 10 mm×10 mm× 1 mm slices from the sintered blocks. Color measurement was performed under black background using spectrophotometer. The chromaticity properties were compared with that of the VITA In-Ceram YZ shade guide. Results Five colored dental zirconia ceramics were obtained. The lightness decreased gradually, and the chroma value increased gradually. The color differences of the two thickness specimens were little. The parameters of the color space were L*:67.76~77.78;a*:-2.19~3.80;b*:12.13~25.01, which was similar with that of the VITA In-Ceram YZ shade guide, while the lowest value of lightness was relatively higher than that of the VITA In-Ceram YZ shade guide. Conclusion Colored 3Y-TZP dental ceramics are suitable for clinical use. There is a need to develop more darkness shaded zirconia dental ceramics.

Key words: dentalceramics, zirconia, color