华西口腔医学杂志 ›› 2015, Vol. 33 ›› Issue (6): 646-650.doi: 10.7518/hxkq.2015.06.020

• 修复工艺学专栏 • 上一篇    下一篇

阳极氧化制备的钛表面不同微观形貌膜层耐腐蚀性研究

霍芳军1,2,3,谢利2,3,童兴野4,王月婷2,3,郭维华2,3,田卫东2,3   

  1. 1.四川大学生命科学学院,成都 610065;2.口腔疾病研究国家重点实验室 华西口腔医院(四川大学);3.口腔再生医学国家地方联合工程实验室(四川大学),成都 610041;4.四川大学材料科学与工程学院,成都 610065
  • 收稿日期:2015-04-15 修回日期:2015-06-18 出版日期:2015-12-01 发布日期:2015-12-01
  • 通讯作者: 田卫东,教授,博士,E-mail:drtwd@sina.com
  • 作者简介:霍芳军,硕士,E-mail:506258588@qq.com
  • 基金资助:
    国际科技合作计划基金资助项目(2011DFA51970);四川省科技支撑计划基金资助项目(2013SZ0185);中国博士后科学基金面上资助项目(2013M531972)

Corrosion resistant properties of different anodized microtopographies on titanium surfaces

Huo Fangjun1,2,3, Xie Li2,3, Tong Xingye4, Wang Yueting2,3, Guo Weihua2,3, Tian Weidong2,3   

  1. 1. College of Life Science, Sichuan University, Chengdu 610065, China; 2. State Key Laboratory of Oral Diseases, West China Hospital of Stomatology, Sichuan University, Chengdu 610041, China; 3. National Engineering Laboratory for Oral Regenerative Medicine, Sichuan University, Chengdu 610041, China; 4. College of Materials Science and Engineering, Sichuan University, Chengdu 610065, China)
  • Received:2015-04-15 Revised:2015-06-18 Online:2015-12-01 Published:2015-12-01

摘要: 目的 探讨阳极氧化制备的钛表面不同微观表面形貌在人工模拟体液中的耐腐蚀性。方法 通过阳极氧化法处理纯钛样品(PT),制备亚微米多孔(S)、微米多孔(M)、微米-亚微米复合多孔(MS)3种不同微观表面形貌氧化钛膜层的样品。采用扫描电子显微镜(SEM)观察样品表面形貌特征,X射线衍射仪分析表面晶型组成,表面粗糙度仪测试表面粗糙度,并对膜层横断面样品行SEM扫描观察膜层横断面结构和测量膜层厚度。采用电化学综合测试系统测试样品在人工模拟体液中的自腐蚀电位(Ecorr)、自腐蚀电流密度(Icorr)和极化电阻(Rp),获得Tafel曲线。结果 阳极氧化对钛样品表面改性获得了微米多孔、亚微米多孔、微米-亚微米多孔3种不同的微观表面形貌。S样品氧化膜中的阻挡层厚度最大。阳极氧化处理后的样品比未处理的纯钛样品的耐腐蚀性增加;阳极氧化处理样品中,耐腐蚀性能由强到弱依次为S样品、M样品、MS样品,S样品的Ecorr最大,Icorr最小,Rp最大,耐腐蚀性能最优。结论 阳极氧化处理可以提高纯钛在人工模拟体液中的耐腐蚀性,亚微米多孔表面钛样品的耐腐蚀性能最优。

关键词: 纯钛, 阳极氧化, 表面形貌, 耐腐蚀性

Abstract: Objective To investigate the corrosion resistant properties of titanium samples prepared by anodic oxidation with different surface morphologies. Methods Pure titanium substrates were treated by anodic oxidation to obtain porous titanium films in micron, submicron, and micron-submicron scales. The surface morphologies, coating cross-sectional morphologies, crystalline structures, and surface roughness of these samples were characterized. Electrochemical technique was used to measure the corrosion potential (Ecorr), current density of corrosion (Icorr), and polarization resistance (Rp) of these samples in a simulated body fluid. Results Pure titanium could be modified to exhibit different surface morphologies by the anodic oxidation technique. The Tafel curve results showed that the technique can improve the corrosion resistance of pure titanium. Furthermore, the corrosion resistance varied with different surface morphologies. The submicron porous surface sample demonstrated the best corrosion resistance, with maximal Ecorr and Rp and minimal Icorr. Conclusion Anodic oxidation technology can improve the corrosion resistance of pure titanium in a simulated body fluid. The submicron porous surface sample exhibited the best corrosion resistance because of its small surface area and thick barrier layer.

Key words: pure titanium, anodic oxidation, surface morphology, corrosion resistant property

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