华西口腔医学杂志

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固态相变对钴铬合金的金瓷匹配性的影响

吴芝凯1 许胜2 李宁1   

  1. 1.四川大学制造科学与工程学院, 成都610059; 2.广西医科大学附属口腔医院齿科技术中心, 南宁530021
  • 收稿日期:2011-12-25 修回日期:2011-12-25 出版日期:2011-12-20 发布日期:2011-12-20
  • 通讯作者: 许胜,Tel:18677198525
  • 作者简介:吴芝凯(1986—),男,四川人,硕士

The effect of solid phase transformation on the metal-ceramic compatibility of Co-Cr alloy

Wu Zhikai1, Xu Sheng2, Li Ning1   

  1. 1. School of Manufacturing Science and Engineering, Sichuan University, Chengdu 610059, China; 2. Dental Technology Center, Affiliated Stomatological Hospital of Guangxi Medical University, Nanning 530021, China
  • Received:2011-12-25 Revised:2011-12-25 Online:2011-12-20 Published:2011-12-20
  • Contact: Xu Sheng,Tel:18677198525

摘要:

目的研究钴铬(Co-Cr)合金在烤瓷过程中发生的固态相变对其金瓷匹配性的影响。方法失蜡法铸造Co-Cr、镍铬(Ni-Cr)合金的片状试件各9个,尺寸为25 mm×3 mm×0.5 mm,其中6个用于测定金瓷结合强度(三点弯曲法),3个去瓷后进行X射线衍射(XRD)分析。铸造2种合金的棒状试件各1个,测定合金的热膨胀系数,并记录冷却曲线。结果Ni-Cr、Co-Cr合金的金瓷结合强度分别为(49.1±3.40)、(40.9±2.02)MPa,二者间的差异具有统计学意义(P=0.00)。Ni-Cr合金与Co-Cr合金在20~500 ℃的平均热膨胀系数分别为13.9×10-6、13.8×10-6·K-1。XRD结果显示,Ni-Cr合金的主要相为奥氏体,Co-Cr合金由fcc相、hcp相及少量σ相组成。结论烤瓷冷却过程中,钴铬合金中的fcc相向hcp相的转变以及σ相的析出导致合金线收缩速度出现突变,降低了金瓷匹配性。

关键词: 金瓷结合, 钴铬合金, 热膨胀系数, 固态相变

Abstract:

Objective To study the effect of solid phase transformation on the metal-ceramic compatibility of Co- Cr alloy during firing programs. Methods 9 foils of Co-Cr and Ni-Cr alloy with the dimension of 25 mm×3 mm×0.5 mm were casted using lost wax technology respectively. Among them, 6 specimens were subjected to metal-ceramic bonding strength test(three point bending method), the ceramic layer of 3 specimens were removed for X-ray diffraction(XRD) analysis. One cylindrical specimen of each alloy was casted for the test of coefficient of thermal expansion, cooling curves were recorded. Results The metal-ceramic bonding strength of Ni-Cr, Co-Cr alloy was (49.1±3.40), (40.9± 2.02)MPa respectively. There was significant difference between the two groups’bonding strength(P=0.00). The coefficient of thermal expansion in the 20-500 ℃ interval of Ni-Cr and Co-Cr alloy was 13.9×10-6, 13.8×10-6·K-1 respectively. XRD analysis indicated that the microstructure of Ni-Cr alloy was austenite. While Co-Cr alloy was constituted by fcc phase, hcp phase and σ phase. Conclusion During the cooling procedure, the transformation of fcc phase to hcp phase and segregation of needle-like σ phase intensify the linear contraction speed of Co-Cr alloy, which decreases
the metal-ceramic adaptability.

Key words: metal-ceramic bonding, Co-Cr alloy, coefficient of thermal expansion, solid phase transformation